Titanite (var. Pr doped) PL/Laser spectrum, 473 nm laser beam, Lenz et al. 2015

Measurement details

Description PL/Laser spectrum of Titanite (var. Pr doped)
Reference Lenz et al. 2015
Lenz C., Nasdala L., Talla D., Hauzenberger C., Seitz R. & Kolitsch U. (2015). Laser-induced REE3+ photoluminescence of selected accessory minerals — An “advantageous artefact” in Raman spectroscopy. Chemical Geology, 415, 1-16. https://doi.org/10.1016/j.chemgeo.2015.09.001
https://www.sciencedirect.com/science/article/pii/S000925411530022X
Material Titanite (var. Pr doped) [ CaTiSiO5:Pr ]
Technique Laser photoluminescence (PL)
Instrument Horiba LabRam HR Evolution
Probe 473 nm laser beam
Det. technology CCD, Si, Peltier cooled
Grating spacing 600 lines/mm
Numerical aperture 0.9
Channel count 8110
Energy range 1.31446 … 2.35597 eV
Intensity range 100 (normalised intensity)
Lines Pr3+ 1.95568 eV (89.2%), 1.97608 eV (40.1%), 1.98631 eV (25.7%), 2.044 eV (65.4%), 2.05363 eV (25%), 2.02689 eV (11.1%), 2.07084 eV (75.8%), 2.1023 eV (9.9%), 1.9092 eV (26.2%), 1.6748 eV (4.9%), 1.41636 eV (100%), 1.42751 eV (70.9%), 1.41271 eV (78.4%), 1.7247 eV (3.2%), 1.8043 eV (2.8%), 1.7568 eV (2.7%)

Composition

Nominal composition of Titanite (var.Pr doped) [ CaTiSiO5:Pr ].
Element Atoms At% Wt%
Ca 1 12.5 20.4
Ti 1 12.5 24.4
Si 1 12.5 14.3
O 5 62.5 40.8

Measurement spectrum

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