Titanite (var. Er doped) PL/Laser spectrum, 473 nm laser beam, Lenz et al. 2015

Measurement details

Description PL/Laser spectrum of Titanite (var. Er doped)
Reference Lenz et al. 2015
Lenz C., Nasdala L., Talla D., Hauzenberger C., Seitz R. & Kolitsch U. (2015). Laser-induced REE3+ photoluminescence of selected accessory minerals — An “advantageous artefact” in Raman spectroscopy. Chemical Geology, 415, 1-16. https://doi.org/10.1016/j.chemgeo.2015.09.001
https://www.sciencedirect.com/science/article/pii/S000925411530022X
Material Titanite (var. Er doped) [ CaTiSiO5:Er ]
Technique Laser photoluminescence (PL)
Instrument Horiba LabRam HR Evolution
Probe 473 nm laser beam
Det. technology CCD, Si, Peltier cooled
Grating spacing 600 lines/mm
Numerical aperture 0.9
Channel count 6950
Energy range 1.48799 … 2.47985 eV
Intensity range 100 (normalised intensity)
Lines Er3+ 2.29992 eV (100%), 2.21783 eV (7.3%), 2.23056 eV (9%), 2.24834 eV (17.4%), 2.25692 eV (5.7%), 2.2612 eV (13.6%), 2.2641 eV (33.6%), 2.27498 eV (19.5%), 2.28157 eV (14.8%), 2.28884 eV (10.1%), 2.2862 eV (8.1%), 2.3592 eV (8.9%), 2.3816 eV (7.9%)

Composition

Nominal composition of Titanite (var.Er doped) [ CaTiSiO5:Er ].
Element Atoms At% Wt%
Ca 1 12.5 20.4
Ti 1 12.5 24.4
Si 1 12.5 14.3
O 5 62.5 40.8

Measurement spectrum

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